I think this makes it more personal and special and I get a chance to explain why these Tweeple are worthy of following. So let's start.
This group is my Social Media life line, and if you're an enthusiast as I am you would follow them too:Chrisbrogan
I follow this group to get tips on graphic design, PhotoShop how to's and techniques:nicholaspatten
I follow this group of photographers for tips on techniques and equipment and just to see their beautiful photos, they're awesome:rmedina
I follow this group because they keep me up to date on everything from technology to art to motherhood. All around an awesome group:Flipbooks
This group I follow for tips on everything from leadership tips to teaching with technology:web20classroom
Being an iPhone fanatic, I follow this group to keep up to date on new or existing iPhone apps, and to get some free redeem codes for free apps:dailyappshow